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铁催化酮类化合物脱氧双硼化制备非末端偕二硼

Zeyu He,Min Fan,Jia'neng Xu, Yue Hu, Lu Wang,Xudong Wu,Chungu Xia,Chao Liu

CHINESE JOURNAL OF ORGANIC CHEMISTRY（2019）

Cited 16|Views21
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Abstract
报道了一种铁催化的酮类化合物的脱氧硼化反应,通过该方法制备一系列的非末端偕二硼化合物,并进一步将该方法应用到克级规模制备中.同时,以常用有机溶剂丙酮为原料制备了相应的非末端偕二硼化合物,并对该偕二硼化合物的C-B键进行选择性单官能团或双官能团化,以验证该类化合物在有机合成中的应用价值.
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Key words
iron catalysis,aliphatic ketone,deoxygenative borylation,gem-diboronate
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