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Bifunctional CuNi/CoOx catalyst for mild-temperature in situ hydrodeoxygenation of fatty acids to alkanes using isopropanol as hydrogen source

Fuel(2020)

引用 36|浏览7
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摘要
•CumNin/CoOx was used for oleic acid hydrodeoxygenation with isopropanol.•100% conversion and 91.3% heptadecane yield were obtained at 240 °C for 8 h.•Strong synergy between Cu, Ni and CoOx favored H2 production ability.•The rate determining step relied on octadecanol dehydrogenation.•Oleic acid hydrodeoxygenation occurred via decarbonylation of stearaldehyde.
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关键词
Biomass-derived fatty acids,Non-noble metals,In situ hydrodeoxygenation,Isopropanol dehydrogenation,Decarbonylation
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