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Physically Correct Configuration Spaces in the Description of the Internal Dynamics of a Rigid Molecule

A. V. Burenin

Optics and Spectroscopy（2019）

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Abstract
A family of configuration spaces in the description of the internal dynamics of a rigid molecule has been considered. It has been shown that the requirement of the physical correctness of the description leads to serious restrictions for such spaces. In particular, only spaces satisfying the Eckart condition are allowed for a nonlinear rigid molecule.
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vibration, rotation, Eckart–Sayvetz conditions
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