Synthesis, crystal structure and theoretical calculation of triphenyltin (IV) polymer based on 2,4-dichlorophenylacrylic acid
INORGANIC AND NANO-METAL CHEMISTRY(2020)
Abstract
Reaction between 2,4-dichlorophenylacrylic acid (HL) and triphenyltin (IV) hydroxide to yield the complex [(Ph3Sn)L](n) (1). The complex has been characterized by elemental analysis, infrared spectrum and single crystal X-ray diffraction. The structural analysis shows that complex 1 possesses 1 D chain structure in which every tin atom is five coordinated. The 1 D chains linked by C(66)-H(66)center dot Cl(2) hydrogen bonds to aggregate in 2 D framework. Additionally, the PXRD, TG, and luminescent property were also investigated. The quantum chemistry calculations was performed with the Gaussian09 program.
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Key words
2,4-dichlorophenylacrylic acid,triphenyltin (IV) polymer,crystal structure,theoretical calculations
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