Zinc(II) thione and selone complexes: The effect of metal redox activity on ligand-based oxidation

Bradley S. Stadelman,Jaime M. Murphy, Amanda M. Owen,Rodrigo Castro-Ramírez, Haydan C. Smith, Caleb M. Cohen, Lynn X. Zhang,Craig A. Bayse,Colin D. McMillen,Noráh Barba-Behrens,Julia L. Brumaghim

Inorganica Chimica Acta（2020）

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摘要

Upon redox-inactive Zn(II) coordination, thione and selone ligands are harder to oxidize than similar complexes with redox-active metals, demonstrating the importance of metal coordination on ligand-based antioxidant activity.

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关键词

Thione,Selone,Zinc,Redox activity,Ligand oxidation

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