Crystal structure and optical absorption properties of Er and Yb doped InTaO4 and InTaO4-yNy as photocatalysts under visible light
Chemical Physics Letters(2020)
摘要
•Er3+ substitution at In3+ sites in the InTaO4 lattice expands light absorption.•In1-xErxTaO4 shows rich absorbance spectra in the visible (400–800 nm) region.•One sub-band gap at about 2.9–3.05 eV, associated to the In:5p-O:2p transitions.•When Er and Yb replace In atoms new states are introduced into the gap.•The localized character of the 4f electrons, does not modify the gap energy.
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关键词
Photocatalysis,Water splitting photocatalysts,Tantalate crystal structure,Weberite-type tantalate,Optical properties of tantalates,Tantalates electronic structure
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