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Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes

Mainak Das,Sangya Chitranshi,M. Murugavel,B. Adinarayana,Cherumuttathu H. Suresh, A. Srinivasan

CHEMICAL COMMUNICATIONS（2020）

Cited 12|Views6
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Abstract
Isosmaragdyrin with an N3C2 core is successfully achieved by introducing a 2,6-di-m-phenylpyridine unit. The core is utilized to stabilize the Rh(i) ion in the N-Rh(i)-N bonding mode and the Pt(ii) ion in the (N boolean AND C)N fashion to form an unsymmetrical pincer-type organometallic complex.
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