Pressure-induced inclusion of neon in the crystal structure of a molecular Cu₂(pacman) complex at 4.67 GPa

Nico Giordano,Christine M. Beavers,Konstantin Kamenev,Jason B. Love,James R. Pankhurst,Simon J. Teat,Simon Parsons

CHEMICAL COMMUNICATIONS（2020）

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摘要

Crystals of a Cu complex of the macrocyclic Schiff-base calixpyrrole or 'Pacman' ligand, Cu-2(L), do not contain any solvent-accessible void space at ambient pressure, but adsorb neon at 4.67 GPa, forming Cu-2(L)center dot 3.5Ne.

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Pressure-induced inclusion of neon in the crystal structure of a molecular Cu2(pacman) complex at 4.67 GPa

Pressure-induced inclusion of neon in the crystal structure of a molecular Cu₂(pacman) complex at 4.67 GPa