Oxidative Dearomative Cross-Dehydrogenative Coupling Of Indoles With Diverse C-H Nucleophiles: Efficient Approach To 2,2-Disubstituted Indolin-3-Ones
MOLECULES(2020)
摘要
The oxidative, dearomative cross-dehydrogenative coupling of indoles with various C-H nucleophiles is developed. This process features a broad substrate scope with respect to both indoles and nucleophiles, affording structurally diverse 2,2-disubstituted indolin-3-ones in high yields (up to 99%). The oxidative dimerization and trimerization of indoles has also been demonstrated under the same conditions.
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关键词
cross coupling,dearomatization,C-H functionalization,indolin-3-ones,dimerization and trimerization of indoles
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