Direct Oxygenation of C-H Bonds through Photoredox and Palladium Catalysis.

JOURNAL OF ORGANIC CHEMISTRY(2020)

引用 27|浏览6
暂无评分
摘要
This report presents the oxygenation of C-H bonds via the merger of photocatalysis and Pd catalysis. Herein, we describe the utilization of a photocatalyst to oxidize an organopalladium(II) intermediate to high-valent Pd-III or Pd-IV intermediates, which promotes the formation of C-O bonds. The demonstrated method works efficiently with various directing groups, such as oxime ether and benzothiazole. The applicability of this direct C-O bond formation method is shown by synthesizing several metal complexes of 2-(benzo[d]thiazol-2-yl)phenol that can be used in organic light-emitting diodes and pharmaceuticals.
更多
查看译文
关键词
photoredox,catalysis,palladium
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要