A facile luminescence resonance energy transfer method for detecting cyano-containing pesticides in herbal medicines
MICROCHEMICAL JOURNAL(2020)
Abstract
It is urgently demanded to establish facile and rapid methods for screening pesticide residues in cultivated herbal medicines to guarantee drug safety. Herein a fluorescent (FL) method was constructed for detecting cyano-containing pesticides by employing the luminescence resonance energy transfer (LRET) behavior between up-conversion nanoparticles (UCNPs) and gold nanoparticles (AuNPs). Negatively-charged citrate-capped AuNPs can be adsorbed onto the surface of positively-charged amino-modified UCNPs by an electrostatic interaction. It resulted in decrease of the FL signal of UCNPs through the LRET process. Cyano-containing pesticides can bind with AuNPs via Au-N=C metal-ligand coordination and remove citrate from the surface of AuNPs. The replacement process induced aggregation of AuNPs and inhibition of LRET. Thus the pesticides can be detected by a facile procedure within 6 min. Acetamiprid, fenpropathrin and chlorothalonil were adopted as model analytes to study the feasibility of the EL method for the detection of cyano-containing pesticides. With the optimum conditions, acetamiprid, fenpropathrin and chlorothalonil can be detected within the ranges of 0.10-100 ng mL(-1), 1.0-100 ng mL(-1) and 0.10-50 ng mL(-1), with detection limits of 0.015 ng mL(-1), 0.24 ng mL(-1) and 0.011 ng mL(-1), respectively. It has been successfully employed to detect acetamiprid in Lanceotata, Angelica dahurica and Astragalus with acceptable recovery values of 76.0%-120.0%, demonstrating its potential for practical application. The work provides a highly efficient methodologic platform for screening pesticide residues in herbal medicines.
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Key words
Upconversion nanoparticles,Gold nanoparticles,Luminescence resonance energy transfer,Pesticide residues,Cyano
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