Synthesis, characterization, and investigation of photochemical properties of tetra-substituted zinc phthalocyanines bearing 4-(3,5-dimethyl-1H-pyrazol-1-yl)phenyl moiety with different linker heteroatoms

Andrey V. Ziminov,Yuri A. Sidunets, Vladimir S. Fundamensky,Vladislav V. Gurzhiy,Stanislav M. Ramsh

Inorganica Chimica Acta（2020）

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Abstract

•The novel zinc phthalocyanines bearing 4-(3,5-dimethyl-1H-pyrazol-1-yl)phenyl groups.•The aggregation behavior of zinc phthalocyanines in water-organic solvent mixtures.•The investigation of the quantum yields of singlet oxygen.•The effect of linker heteroatom on the photophysical and photochemical properties.

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Key words

Zinc phthalocyanine,Phthalonitrile,Pyrazole,Linker heteroatom,X-ray analysis,Solvatochromic effect,Aggregation,Mixed solvents,Quantum yield of singlet oxygen

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