Unravelling the Reaction Mechanism of Gas-Phase Formic Acid Decomposition on Highly Dispersed Mo2C Nanoparticles Supported on Graphene Flakes
Applied Catalysis B: Environmental（2020）
Abstract
•Used cubic molybdenum carbide nanoparticle material to study reactions of formic acid.•Evidence for gas-surface species interaction mechanism for formic acid dehydration.•Supported by Monte Carlo style simulation which replicates experimental observations.
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Key words
Molybdenum carbide,Formic acid decomposition,CO2/CO selectivity,Monte carlo simulations,Eley-Rideal type mechanism
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