Preparation of MCM-41-supported Pd–Pt catalysts with enhanced activity and sulfur resistance for partial hydrogenation of soybean oil-derived biodiesel fuel

Applied Catalysis A: General(2020)

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摘要
•MCM-41-supported Pd–Pt catalysts made for partial hydrogenation of BDF in H-FAME.•H-FAME is a new biodiesel fuel enriched in monounsaturated FAME for high blends.•Pd–Pt catalyst with Pd/Pt = 1 yielded the highest activity in synthesis of H-FAME.•Catalyst showed the highest sulfur resistance and lowest degree of oversaturation.•This H-FAME with proper composition can meet international fuel standards.
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关键词
Partial hydrogenation,MCM-41,Noble metals,Sulfur tolerance,Pd–Pt alloy,Rate constant
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