A novel low-bandgap pyridazine thiadiazole-based conjugated polymer with deep molecular orbital levels
POLYMER CHEMISTRY(2020)
Abstract
A pyridazine thiadiazole acceptor (PzT) has been utilised in the synthesis of a novel low band-gap D-A copolymer PTTPz. It is a much stronger acceptor in comparison to BT and PyT moieties widely incorporated in the literature. Experimental results reveal that per electronegative N atom that is substituted into the acceptor, an effective HOMO and LUMO stabilization energy of similar to 0.2-0.1 eV can be achieved.
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Key words
polymer,molecular,low-bandgap,thiadiazole-based
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