Experimental Stark widths of Mo I and Mo II spectral lines in visible region

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS(2020)

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摘要
In the last decade, molybdenum became a very important element for understanding the process of nucleosynthesis. An essential requirement for stellar spectral analysis is the availability of high-quality atomic data, including Stark broadening parameters. In this work we investigate Stark broadening of molybdenum spectral lines from the wavelength range 370 nm-510 nm. This is the first presentation of Stark widths for 18 Mo I and 18 Mo II spectral lines measured at an electron density of 1.5 x 10(23) m(-3) and electron temperature of 13000 K. Laser induced plasma with well isolated molybdenum spectral lines is employed as a radiation source. Spectra are recorded side-on; the line profiles are obtained via inverse Abel transform. Electron temperature is estimated using the Saha-Boltzmann method. To estimate electron density we applied two techniques. The first is based on the Saha-Boltzmann method for selected Mo I and Mo II spectral lines. In the second approach we rely on the measured width of the well-researched He I 388.86 nm line, as well as on the peak separation of the He I 447.15 nm line. Stark widths normalized to 1 x 10(23) m(-3) electron density are also given. The possible influence of isotope shift and hyperfine structure on spectral line profiles is discussed in detail. Stark shifts of investigated Mo I and Mo II spectral lines, if they exist, are below the detection limit of the experimental setup.
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关键词
atomic data,line profiles,Stark broadening,LIBS
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