Sensitizing, sensing and chemical separation of Tb(III) ions: All in a novel copper metal-organic framework

Materials Research Bulletin(2020)

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摘要
•A novel CuMOF, [Cu2(3,4-pydc)2(H2O)5]n.2nH2O (1), has been synthesized.•Compound 1 exhibited efficient sensitizing and sensing ability for Tb3+ ions.•The mechanism of adsorption of Tb3+ ions is cation exchange due to the special geometry of 1.•Compound 1 can be utilized as a long-term sensor and adsorbent for Tb3+ ions.
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关键词
Metal-organic framework,Chemical sensing and separation,Fluorescence,Terbium,Copper,Cation exchange
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