Anion mediated switching from mono- to polymer structure in copper(II) complexes with 4,6-dimethylpyrimidinylhydrazone 1-phenyl-3-methyl-4-formylpyrazol-5-one

Sergey N. Lyubchenko,Igor N. Shcherbakov,Yulia P. Tupolova,Leonid D. Popov,Sergey I. Levchenkov,Andrey N. Morozov,Sergey A. Borodkin,Vladimir A. Lazarenko,Victor N. Khrustalev,Yan V. Zubavichus,Vadim V. Minin

Inorganica Chimica Acta（2020）

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摘要

•Cu(II) Complexes were synthesized based on hetarylhydrazone pyrazol-5-one derivative.•The structure of the compounds were studied by experimental and theoretical methods.•Mono- or polymer structure of complexes Cu(II) is dependent on salt anion.

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关键词

Hetarylhydrazone,Pyrazolone,Cu(II) complex,Crystal structure,DFT

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