Identification and characterization of an anthrol reductase from Talaromyces islandicus (Penicillium islandicum) WF-38-12
GREEN CHEMISTRY(2019)
Abstract
An NADPH-dependent oxidoreductase from Talaromyces islandicus WF-38-12 has been identified through genome analysis. It has been shown to catalyze a regio- and stereoselective reduction of anthrols (formed in situ by the reduction of anthraquinones in the presence of Na2S2O4) to (R)-dihydroanthracenones, with high enantiomeric excess (>99%). The implications of results on the bio-synthesis of deoxygenated (bis)anthraquinones and modified (bis) anthraquinones are discussed.
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Key words
anthrol reductase
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