Ring size matters: supramolecular isomerism in self-assembled redox-active tetra- and hexaruthenium macrocycles.
CHEMICAL COMMUNICATIONS(2020)
Abstract
Self-assembly of a divinylthiophene-bridged diruthenium complex with 2,5-furandicarboxylate leads to the formation of two macrocyclic structures that differ solely with regard to their respective nuclearities. Both supramolecular isomers were fully characterized and the conversion of the hexa- to the tetraruthenium macrocycle was followed by NMR monitoring.
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Key words
hexaruthenium macrocycles,supramolecular isomerism,self-assembled,redox-active
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