A convenient synthesis of 2,5-diaroyl-4-hydroxy cyclopent-2-enones incorporating aromatic and heteroaromatic moieties
SYNTHETIC COMMUNICATIONS(2019)
摘要
The base-catalyzed reaction of 1,5-diphenyl-pentane-1,3,5-trione with aromatic/heteroaromatic 1,2-diones leading to the synthesis of 2,5-diaroyl-4-hydroxycyclopent-2-enones and its conversion to 2,5-diaroylcyclopentadienones is reported here. 2,5-Dibenzoyl-4-hydroxycyclopent-2-enone and 2,5-dithenoyl-4-hydroxycyclopent-2-enone are valuable compounds which act as chemosensors for selective detection of Fe3+ and Cu2+, respectively.
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关键词
Benzil,cyclopentadienones,1,5-diphenyl-pentane-1,3,5-trione,4-hydroxy cyclopent-2-enones,thenil
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