Asymmetric Wacker-Type oxyallenylation and Azaallenylation of Cyclic Alkenes.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2020)
摘要
Palladium-catalyzed three-component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker-type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well as some electron-poor aryl amines.
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关键词
allenes,asymmetric catalysis,carboetherification,palladium catalysis,Wacker reaction
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