Chemical recycling of polyenaminones by transamination reaction via amino–enaminone polymerisation/depolymerisation

Anže Zupanc,Tomaž Kotnik,Urša Štanfel,Helena Brodnik Žugelj,Anja Kristl,Aleš Ručigaj,Lev Matoh,David Pahovnik,Uroš Grošelj,Till Opatz,Franc Požgan,Bogdan Štefane,Ema Žagar,Jurij Svete

European Polymer Journal（2019）

引用 5|浏览14

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摘要

•Mild reaction conditions, step-wise polymerisation, Mw ~ 3.000 Da.•Facile depolymerisation with dimethylamine, closed-loop recycling.•Porous microstructure, insoluble, film forming and UV-shileding properties.•Tunability of polymer structure.•Broad substrate availability, combinatorial synthesis feasible.

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关键词

Polyenaminones,‘click’ polymerisation,Depolymerisation,Recyclability,Sustainable chemistry

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