High sensitivity spectroscopy of the O2 band at 1.27 µm: (II) Air-broadened line profile parameters

Journal of Quantitative Spectroscopy and Radiative Transfer(2020)

Cited 10|Views35
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Abstract
•Spectra of air-broadened O2 in the 1.27 µm band were measured by CRDS referenced to a frequency comb.•Line intensity and line-shape parameters were retrieved for 85 lines with the speed-dependent Nelkin-Ghatak profile.•Line-mixing effect was evidenced and measured for lines in the Q branch region.•The results reveal several differences with data from HITRAN and existing studies.•The retrieved high-order line-shape parameters are in good agreement with predictions from molecular dynamics simulations.
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Key words
Oxygen band at 1.27 µm,Cavity ring-down spectroscopy,Line intensity,Line-shape,Speed dependence,Dicke narrowing,Line mixing,Speed-dependent Nelkin-Ghatak profile,Air broadening
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