Na2CO3-promoted thioesterification via N–C bond cleavage of amides to construct thioester derivatives:

Jiasi Tao,Weijie Yu,Jin Luo,Tao Wang, Wanling Ge,Ziwei Zhang,Bingjie Yang,Fei Xiong

JOURNAL OF CHEMICAL RESEARCH（2019）

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摘要

A mild, efficient, and transition-metal-free catalytic strategy is developed to construct thioesters via selective N-C bond cleavage of Boc(2)-activated primary amides. This strategy is successfully carried out with stoichiometric Na2CO3 as the base and provides the corresponding products in moderate to excellent yields.

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关键词

selective N-C bond cleavage,stoichiometric Na2CO3,thioesters,transition-metal-free catalytic strategy

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