Catalytic conversion of CO2 to propylene carbonate over Pt-decorated Mg-substituted metal organic framework
Applied Catalysis A: General（2019）
Abstract
•Pt nanoclusters are shown to preferentially form at MOF crystallite edge sites indicative of Pt-MOF-74 ligand formation.•Propylene oxide conversion and propylene carbonate selectivity were shown systematically increase with Pt loading.•A synergetic effect was observed between the Pt10/Mg-MOF-74 catalyst and the co-catalyst solvents used to activate CO2.
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Key words
CO2Pt nanoparticles,MOF,Porous coordination polymer,Cyclic carbonate,Cycloaddition
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