Design and synthesis of chiral hyperbranched polymers containing cinchona squaramide moieties and their catalytic activity in the asymmetric Michael addition reaction

Journal of Catalysis(2019)

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摘要
•Chiral hyperbranched polymers (HBPs) having cinchona squaramide were synthesized.•Excellent catalytic activity of HBPs in asymmetric Michael addition.•Almost perfect enantioselectivity (>99% ee) achieved in the reaction.•Robustness and reusability without any significant decrease in catalytic activity.
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关键词
Chiral hyperbranched polymer,Cinchona squaramide,Mizoroki–Heck polymerization,Asymmetric Michael reaction
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