Mössbauer study of non-stoichiometric FeCr2S4 system

Journal of Molecular Structure(2020)

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Abstract
A partial spin transition stimulated by spontaneous symmetry breaking has been observed, for the first time, in the non-stoichiometric chalcogenide spinel FeCr2S4. A Fe2+ high spin - low spin transition HS-LS: S = 2 → S = 0 is detected below the Néel temperature TN in the magnetic subsystem corresponding to a part of the sample with deviations from stoichiometry. The fraction of diamagnetic Fe atoms increases with decreasing temperature.
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Key words
Spin transition,Jahn-teller effect,Non-stoichiometric compound,Mössbauer spectroscopy
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