Nanopowders explosion: Influence of the dispersion characteristics

This work aims to study the influence of the dispersion conditions in a standard 20L sphere on the explosibility of a nanopowder. Even more than for micropowders, the dispersion conditions have a strong impact on the dust cloud homogeneity and its particle size distribution (PSD). Due to their high surface energy, nanoparticles are prone to agglomeration, but such structures can be broken during the dispersion process. Varying the dispersion procedure, the ignition delay time and even the nozzle type (rebound or symmetric) leads to modifications of the dust specific surface area, and thus of its reactivity. Tests were performed on aluminum and carbon black nanopowders. They were characterized before and during their dispersion in the sphere, notably using in situ laser PSD measurement. The initial turbulence level of the dust cloud was determined by particle image velocimetry. A lower shear stress is exerted on the agglomerates by using the symmetric nozzle, which causes less fragmentation and decreases the explosion severity. However, the results obtained with this nozzle are more reproducible than with the rebound nozzle.