Heteroleptic copper(I) complexes incorporating sterically demanding diazabutadiene ligands (DABs). Synthesis, spectroscopic characterization and solid state structural analysis

Anastasios Peppas,Evanthia Papadaki,Gregor Schnakenburg,Victoria Magrioti,Athanassios I. Philippopoulos

Polyhedron（2019）

Cited 8|Views10

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Abstract

The synthesis and characterization of new copper(I) complexes of the general formula [Cu(RDABdipp)(LCOOMe)](PF6) is described. These are rare examples of heteroleptic copper(I) complexes comprising the 1,4-diaza-1,3-butadiene ligand (RDABdipp, R = H, Me; dipp = 2,6-diisopropylphenyl) and an ancillary α-diimine ligand (LCOOMe = methyl-2-(pyridin-2-yl)-quinoline-4-carboxylate).

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Key words

1,4-Diaza-1,3-butadienes,Methyl-2-(pyridin-2-yl)-quinoline-4-carboxylate,Sterically demanding ligands,Copper(Ι) complexes,Heteroleptic complexes

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