Heteroleptic copper(I) complexes incorporating sterically demanding diazabutadiene ligands (DABs). Synthesis, spectroscopic characterization and solid state structural analysis
Polyhedron(2019)
Abstract
The synthesis and characterization of new copper(I) complexes of the general formula [Cu(RDABdipp)(LCOOMe)](PF6) is described. These are rare examples of heteroleptic copper(I) complexes comprising the 1,4-diaza-1,3-butadiene ligand (RDABdipp, R = H, Me; dipp = 2,6-diisopropylphenyl) and an ancillary α-diimine ligand (LCOOMe = methyl-2-(pyridin-2-yl)-quinoline-4-carboxylate).
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Key words
1,4-Diaza-1,3-butadienes,Methyl-2-(pyridin-2-yl)-quinoline-4-carboxylate,Sterically demanding ligands,Copper(Ι) complexes,Heteroleptic complexes
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