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Synthesis and characterisation of new Ni2Mn, Ni2Mn2 and Mn8 clusters by the use of 2-pyridyl oximes

Polyhedron(2019)

Cited 5|Views25
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Abstract
Ni2Mn (1), Ni2Mn2 (2) and Mn8 (3) species are reported from the employment of methyl-2-pyridyl oxime (in 1 and 2) and phenyl-2-pyridyl oxime (in 3). 1 and 2 are the first examples of a 3d–3d′ heterometallic cluster bearing the methyl-2-pyridyl oxime and exhibit a diamagnetic ground state. 3 contains 4 oxo-bridges and is a new member of the small family of high nuclearity Mn/(py)C(ph)NO− complexes.
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Key words
2-Pyridyl oximes,3d–3d′ mixed metal clusters,Magnetism,Ni/Mn compounds,Crystal structures
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