New magnetic nanomaterials based on ferrocene-containing polymers synthesized under ultrasonic irradiation

R. A. Dvorikova,A. S. Peregudov,A. A. Korlyukov,M. I. Buzin,I. V. Nagornova,V. A. Vasnev

Russian Chemical Bulletin（2019）

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Abstract

A new magnetic nanomaterial was obtained based on soluble ferrocene-containing poly-phenylene synthesized under ultrasonic irradiation at room temperature. The maximum magnetization of the nanomaterial containing magnetite nanoparticles was 23 G cm 3 g −1 in a magnetic field of 2.5 kOe. According to transmission electron microscopy results, the average size of the magnetic nanoparticles was 19 nm.

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Key words

ultrasonic treatment,cyclocondensation reaction,ferrocene-containing polymer,1,3,5-triferrocenylbenzene,1,3-diferrocenylbenzene,nanomaterial,thermal degradation,magnetization,NMR spectroscopy,powder X-ray diffraction

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