Double perovskite PrBaCo2O5.5: An efficient and stable electrocatalyst for hydrogen evolution reaction
Journal of Power Sources(2019)
Abstract
In this work, we successfully demonstrate that a crystal-structure regulation by simply altering the annealing temperature might be an effective way to enhance the electrocatalytic activity of perovskite oxides. We report a high-performance electrocatalyst with an orthorhombic double perovskite structure (i.e., PrBaCo2O5+δ, δ = ∼0.52), which shows superior activity and durability towards hydrogen evolution reaction in comparison to a cubic perovskite oxide (i.e., Pr0.5Ba0.5CoO3-δ) and a tetragonal one (i.e., PrBaCo2O5+δ, δ = ∼0.76), despite the similar composition. The improvement of the electrocatalytic activity for hydrogen evolution reaction is mainly attributed to a high-degree structure distortion resulted from the high oxygen vacancy concentration, a large electrochemical active surface area, and a low charge transfer resistance. In addition, lattice oxygen species may provide an extra contribution to the enhancement of the hydrogen evolution reaction for Pr0.5Ba0.5CoO3-δ sintered at 1000 °C. Furthermore, a considerable correlation between O p-band centers and HER overpotentials is observed, and PBC-1100 with the highest O p-band center exhibits the best HER activity. These results indicate that the electrochemical performance of perovskite oxides could be effectively enhanced. Especially orthorhombic double perovskite oxides could be a new class of promising electrocatalysts.
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Key words
Perovskite oxide,Double perovskite,Crystal structure,Annealing temperature,Hydrogen evolution reaction
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