Silver-catalyzed Glaser coupling of alkynes
APPLIED ORGANOMETALLIC CHEMISTRY(2015)
Abstract
Excellent yields were obtained from the silver nitrate-catalyzed homocoupling reaction of alkynes in N,N-dimethylformamide using triphenylphosphine as ligand. This safe and simple silver catalytic system has been employed in a safe and efficient protocol for the synthesis of various 1,3-diyne products from the corresponding aromatic or aliphatic alkynes with good air stability and absence of side products. Copyright (c) 2015 John Wiley & Sons, Ltd.
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Key words
alkynes,Glaser coupling,silver catalysis
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