Microstructural effects on the high-temperature steam oxidation resistance of magnetron sputtered Cr-Al-Si-N quaternary coatings on zirconium coupons
Surface and Coatings Technology(2019)
Abstract
It is of great significance to develop accident tolerant fuel claddings for enhancing the safety margin of light water reactors. Cr-Al-Si-N quaternary coatings were proposed to improve the mechanical properties and the high-temperature steam oxidation resistance of Zr-based alloys. (Cr0.6Al0.3Si0.1)xN1−x coatings with three kinds of microstructure, were prepared on Zr coupons, and then were evaluated on their mechanical properties and oxidation resistance in the high-temperature steams. The “dense & column-free” coating exhibits a combination of the best mechanical properties and the highest oxidation resistance. In comparison with the Zr coupon, its hardness H and indentation modulus E* increased by ~4 times and ~twice, respectively. After coated with the “dense & column-free” coating, the oxidation of the Zr coupon was completely suppressed in the 1000 °C steam for 15 min, and the thickness of the α-Zr(O) layer deceased by 40%–92% in the 1200 °C steam for 30 min. By contrast, the “porous & columnar” coating hardly provided any protection for the underneath Zr substrate in the high-temperature steams. The result demonstrates that the densely fine-grained or amorphous microstructure could effectively suppress inner-diffusion of O atoms and favor formation of a dense and coherent scale on surface, which would be highly desirable for the protection coatings of Zr claddings.
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Key words
Cr-Al-Si-N quaternary coatings,Magnetron sputtering,High-temperature steam oxidation resistance,Accident tolerant fuel Zr claddings
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