Two-in-One Strategy for the Pd(II)-Catalyzed Tandem C–H Arylation/Decarboxylative Annulation Involved with Cyclic Diaryliodonium Salts
Organic Letters(2019)
摘要
We report here a two-in-one strategy for the Pd(II)-catalyzed tandem C–H arylation/decarboxylative annulation between readily available cyclic diaryliodonium salts and benzoic acids. The carboxylic acid functionality can be used as both a directing group for the ortho-C–H arylation and the reactive group for the tandem decarboxylative annulation. By a step-economical double cross-coupling annulation procedure, the privileged triphenylene frameworks were efficiently constructed, which have potential applications in material chemistry.
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关键词
Directed C–H Functionalization
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