Preparation and Reaction Mechanism Characterization of Alkali-activated Coal Gangue-Slag Materials.

In this paper, slag is used as a calcium source to make alkali-activated coal gangue slag (AACGS) based material. The reaction mechanism of AACGS materials was discussed in depth by means of XRD, FT-IR, 29Si MAS-NMR (nuclear magnetic resonance) and SEM-EDS (energy dispersive spectrometer). The experimental results show that coal gangue can be used as a raw material for preparing alkali-activated materials. The liquid solid ratio is the most influential factor on AACGS paste fluidity and strength, followed by slag content. As the modulus of sodium hydroxide increases, the depolymerization process of the reactant precursor is accelerated, but the high sodium hydroxide concentration inhibits the occurrence of the early coal gangue slag polycondensation reaction, and exerts little effect on the 28 d compressive strength. Ca2t in the slag promotes exchange with Nat, and the product is converted from N-A-S-H gel to C-(A)-S-H gel, and C-(A)-S-H is formed with higher Ca/Si ratio with the increase of slag content. The slight replacement of coal gangue by slag can greatly improve the reaction process and the strength of AACGS materials.