Synthesis of Novel C 2-Symmetric Sulfur-Based Catalysts: Asymmetric Formation of Halo- and Seleno-Functionalized Normal- and Medium-Sized Rings
SYNLETT(2019)
Abstract
The synthesis of novel, highly functionalized, C (2) -symmetric sulfur-based catalysts is developed and their catalytic applications are explored in asymmetric bromo-, iodo- and seleno-functionalizations of alkenoic acids. This protocol provides the corresponding normal- and medium-sized bromo, iodo and selenolactones in up to 98% yield and 83% stereoselectivity.
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Key words
alkenoic acids,organosulfur catalysts,asymmetric catalysis,halolactones,selenolactones
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