A novel approach to unfold the heavily overlapped spectrum of a diatomic molecule: Monte Carlo random walk routine

W.Q. Xu,Y.W. Liu, T. Xiong,X.C. Huang,S.X. Wang, X.X. Mei,X. Sun, X. Shi,L.F. Zhu

Journal of Electron Spectroscopy and Related Phenomena（2019）

引用 4|浏览28

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摘要

•A novel procedure was established to unfold the heavily overlapped spectrum.•Overcoming difficulties due to the invalidity of Franck-Condon approximation.•Highly increasing the probability of the global minimum searching.

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关键词

Monte Carlo random walk,Multiparameter fitting,Franck-Condon factors,Optical oscillator strengths,Deuterium

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