The effect of Al³⁺ coordination structure on the propane dehydrogenation activity of Pt/Ga/Al₂O₃ catalysts

The effect of the Al2O3 structure on the performance of Pt/Ga/Al2O3 catalysts is investigated for the direct dehydrogenation of propane. The study unveils that the structure of Al3+ determines the bulk structure of catalysts, particularly a high content of coordinatively unsaturated Al3+ sites (penta-coordinated Al3+, denoted as Al-penta(3+)) could lead to a remarkably improved dehydrogenation activity of the catalyst. The bulk characterization reveals that the sufficient amount of Al-penta(3+) penta in Al2O3 benefit the dispersion of Pt and Ga2O3 on the Al2O3 support. At the same time, TPR results reveal that the presence of Pt facilitates the reduction of Ga2O3, likely due to the hydrogen spillover between the well dispersed Pt and Ga2O3, which consequently enhances the synergistic function between Pt and Ga2O3 in the dehydrogenation of propane. Recyclability tests demonstrate that the dehydrogenation activity stabilizes after three cycles over the Pt/Ga/Al2O3 catalyst. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier By, and Science Press. All rights reserved.