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Construction of polycyclic bridged indene derivatives by a tandem 1,3-rearrangement/intramolecular Friedel-Crafts cyclization of propargyl acetates.

Jiantao Zhang,Zhehui Liao,Lianfen Chen,Huanfeng Jiang,Shifa Zhu

CHEMICAL COMMUNICATIONS（2019）

Cited 12|Views4
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Abstract
An unprecedented Lewis acid-catalyzed cascade 1,3-rearrangement/Friedel-Crafts cyclization of propargyl acetates is developed for the construction of polycyclic bridged indene derivatives in moderate to good yields. This practical procedure features mild conditions, broad substrate scope, and easy operation.
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indene derivatives,friedel–crafts cyclization,13-rearrangement/intramolecular friedel–crafts
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