Enantioselective formal synthesis of (+)-madangamine A.
CHEMICAL COMMUNICATIONS(2019)
摘要
An enantioselective formal synthesis of the marine alkaloid madangamine A using phenylglycinol-derived lactam 1 as the starting enantiomeric scaffold is reported. The synthesis involves the construction of the C-9 substituted diazatricyclic ABC core and the final closure of D and E rings from the polyunsaturated skipped intermediate 19.
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关键词
enantioselective formal synthesis
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