Mixed proton and electron conducting double perovskite anodes for stable and efficient tubular proton ceramic electrolysers

Hydrogen production from water electrolysis is a key enabling energy storage technology for the large-scale deployment of intermittent renewable energy sources. Proton ceramic electrolysers (PCEs) can produce dry pressurized hydrogen directly from steam, avoiding major parts of cost-driving downstream separation and compression. However, the development of PCEs has suffered from limited electrical efficiency due to electronic leakage and poor electrode kinetics. Here, we present the first fully operational BaZrO 3 -based tubular PCE, with 10 cm 2 active area and a hydrogen production rate above 15 Nml min −1 . The novel steam anode Ba 1− x Gd 0.8 La 0.2+ x Co 2 O 6− δ exhibits mixed p-type electronic and protonic conduction and low activation energy for water splitting, enabling total polarization resistances below 1 Ω cm 2 at 600 °C and Faradaic efficiencies close to 100% at high steam pressures. These tubular PCEs are mechanically robust, tolerate high pressures, allow improved process integration and offer scale-up modularity.