High-Lithium-Affinity Chemically Exfoliated 2D Covalent Organic Frameworks.

Covalent organic frameworks (COFs) with reversible redox behaviors are potential electrode materials for lithium-ion batteries (LIBs). However, the sluggish lithium diffusion kinetics, poor electronic conductivity, low reversible capacities, and poor rate performance for most reported COF materials limit their further application. Herein, a new 2D COF (TFPB-COF) with six unsaturated benzene rings per repeating unit and ordered mesoporous pores (approximate to 2.1 nm) is designed. A chemical stripping strategy is developed to obtain exfoliated few-layered COF nanosheets (E-TFPB-COF), whose restacking is prevented by the in situ formed MnO2 nanoparticles. Compared with the bulk TFPB-COF, the exfoliated TFPB-COF exhibits new active Li-storage sites associated with conjugated aromatic pi electrons by facilitating faster ion/electron kinetics. The E-TFPB-COF/MnO2 and E-TFPB-COF electrodes exhibit large reversible capacities of 1359 and 968 mAh g(-1) after 300 cycles with good high-rate capability.