Di-manganese(0) Carbonyl Mediated Azo Bond Cleavage and Recombination Reaction in Azo-aromatic Ligand: An Effect of Extended Phenolate Donor

Ipsita Chatterjee,Mou Chakraborty,Santi Prasad Rath,Tanushri Saha,Pradip Ghosh, Subhas Samanta,Sreebrata Goswami

Polyhedron（2019）

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摘要

The chemical reactivities of 2,4-di-tert-butyl-6-(pyridin-2-ylazo)-phenol (HL1) towards two different Mn precursors are reported. Redox-induced azo bond cleavage followed by oxidative recombination of amido functions have occurred in the reaction with Mn2(CO)10 while azo-anion radical complex is formed in case of Mn(II) precursor.

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关键词

Manganese complexes,Azoaromatic ligand,Azo-bond cleavage,Redox,DFT studies

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