Reduction of furfural by Mn/2,4,6‐Coll . HCl/H 2 O: Mechanistic aspects of this reaction

APPLIED ORGANOMETALLIC CHEMISTRY(2019)

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摘要
The reduction of furfural to furfuryl alcohol is carried out for the first time by the Mn/2,4,6-Coll(.)HCl/H2O system. New experimental observations and DFT calculations indicate that the reduction takes place via hydrolysis of a metallaoxirane intermediate.
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关键词
furfural,Furfuryl alcohol,green chemistry,manganese,reduction reaction
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