Water wire clusters in isostructural Cu(II) and Ni(II) complexes: Synthesis, characterization, and thermal analyses
Inorganica Chimica Acta（2019）
Abstract
•Isostructural Cu(II) and Ni(II) complexes with discrete hydrogen bonding motifs.•Hydrogen bonding network confines water molecules to coiled 1D chains.•Thermal properties of hydrated structures correlate with hydrogen bonding.•Orientation of metal stacks support propagation of charge carriers.
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Key words
Hydrogen bonding,Water wires,Copper,Nickel,1-Methylimidazole
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