Phosphine-ligated Ir(III)-complex as a bi-functional catalyst for one-pot tandem hydroformylation-acetalization

Huan Liu,Lei Liu,Wen-Di Guo,Yong Lu,Xiao-Li Zhao,Ye Liu

Journal of Catalysis（2019）

引用 16|浏览13

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摘要

IrCl3⋅3H2O with the involvement of the electron-deficient phosphines (L1-L6) was able to serve as a bi-functional catalyst with dual functions of transition metal complex and IrIII-Lewis acid for tandem hydroformylation-acetalization of olefins.

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关键词

Hydroformylation,Acetalization,Tandem reaction,Iridium complex,Bi-functional catalyst,Co-catalysis,Electron-deficient phosphine

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