Phosphotungstic acid anchored on amine-functionalized MIL-101: An effective catalyst for the direct esterification of 1-butene to sec-butyl acetate

Journal of the Taiwan Institute of Chemical Engineers(2019)

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摘要
•Amino groups were used to anchor HPW on MIL-101 via the charge effect.•HPW was highly dispersed on the amine-functionalized MIL-101.•The as-prepared catalyst exhibited superior SBAC yield for olefin esterification.•40 wt% HPW/EDG-MIL-101 had optimal activity and good stability.
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关键词
Phosphotungstic acid,Ethylenediamine grafted MIL-101,Charge interaction,Dispersion,Olefin esterification
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