Structurally bound S2−, S1−, S4+, S6+ in terrestrial apatite: The redox evolution of hydrothermal fluids at the Phillips mine, New York, USA
Ore Geology Reviews(2019)
Abstract
•Four oxidation states of Sulfur found in natural apatite (S2−, S1−, S4+, S6+).•Sulfur contents in apatite correlate positively with abundance of oxidized S.•Monazite and REE patterns fingerprint fluid-induced dissolution-reprecipitation processes.•Sulfur oxidation states in apatite elucidate redox evolution of hydrothermal systems.
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Key words
Apatite,Sulfur oxidation states,Sulfur micro-XANES,Oxygen fugacity,Rare earth elements,Hydrothermal ore deposits
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